Relative molar mass distributions of chromophoric colloidal organic matter in coastal seawater determined by Flow Field-Flow Fractionation with UV absorbance and fluorescence detection     

Martin Hassellv 《Marine Chemistry》2005,94(1-4):111

A new method for the characterization of chromophoric colloidal organic matter in seawater has been applied to samples from the Baltic Sea, Kattegatt and Skagerrak seas. Size fractionation of the sample by Flow Field-Flow Fractionation and measurement of the fluorescent and UV absorbing properties of the individual size fractions result in a relative molar mass distribution (RMM) of the optical properties. The RMM distributions have been used to estimate number and weight average relative molar masses, and polydispersity indices. At least two sources of coloured organic matter were identified from the ratio of fluorescence to UV: the Baltic surface water and the Skagerrak deep water. The dominating processes were mixing and dilution, but processes such as photo bleaching of fluorescence are also believed to be important. The RMM distribution derived from UV detection (1150–1300 Dalton) increased with increasing salinity while that derived for fluorescence (1500–1250 Dalton) decreased with increasing salinity. The specific UV absorbance taken as a proxy of the aromaticity of the chromophoric organic material showed decreasing trend with both increasing salinity and increasing UV derived weight average relative molar mass. Increasing polydispersity of the colloidal material was also observed as a function of salinity.  相似文献   

纳米碳酸钙材料的工业合成与应用     

姬泓巍  徐环  辛惠蓁  宁霞 《中国海洋大学学报(自然科学版)》2002,32(4):634-640

该文对目前工业上生产纳米碳酸钙的方法作了较为详细的综述。对一步碳化法、两步碳化法、多段喷雾碳化法、旋转填充床碳化反应器碳化技术制备链形、纺锤形、球形、立方形等不同形状的纳米碳酸钙材料的方法进行了比较和总结  相似文献   

Nitrogen forms and decomposition of organic carbon in the southern Bohai Sea core sediments   总被引：5，自引：0，他引：5  

Song Jinming  Ma Hongbo  L&#; Xiaoxia 《海洋学报(英文版)》2002,21(1):125-133

Study on form characteristics of nitrogen in marine sediments is the primary method to research its biogeochemical cycling and nitrogen form characteristics in core sediments can reflect the process and results of early diagenesis in a certain degree. In this paper, Sequential extraction process in natural grain size was used for studying the existent forms of nitrogen in five core sediments of the southern Bohai Sea for the first time. Nitrogen was divided into two parts -transferable and fixed based on whether it could be extracted by the reagent. Distributions and early diagenesis of transferable nitrogen forms in the southern Bohai Sea were researched integratedly. Results indicate that IEF - N and OSF-N are predominant forms in transferable part in the studied core sediments. Contents of different nitrogen forms vary differently with depth, and have different diagenesis process. Decomposition constant of organic nitrogen (ON) and OC are about 15.51 × 10~(-3)a~(-1)and 4.79× 10~(-3)a~(-1) respective  相似文献   

Sources and distribution of organic matter in a river-dominated estuary (Winyah Bay, SC, USA)   总被引：12，自引：0，他引：12  

Miguel A. Goi  Maria J. Teixeira  David W. Perkey 《Estuarine, Coastal and Shelf Science》2003,57(5-6):1023-1048

The sources and distribution of organic matter (OM) in surface waters and sediments from Winyah Bay (South Carolina, USA) were investigated using a variety of analytical techniques, including elemental, stable isotope and organic biomarker analyses. Several locations along the estuary salinity gradient were sampled during four different periods of contrasting river discharge and tidal range. The dissolved organic carbon (DOC) concentrations of surface waters ranged from 7 mg l⁻¹ in the lower bay stations closest to the ocean to 20 mg l⁻¹ in the river and upper bay samples. There was a general linear relationship between DOC concentrations and salinity in three of the four sampling periods. In contrast, particulate organic carbon (POC) concentrations were significantly lower (0.1–3 mg l⁻¹) and showed no relationship with salinity. The high molecular weight dissolved OM (HMW DOM) isolated from selected water samples collected along the bay displayed atomic carbon:nitrogen ratios ([C/N]a) and stable carbon isotopic compositions of organic carbon (δ¹³C_OC) that ranged from 10 to 30 and from −28 to −25‰, respectively. Combined, such compositions indicate that in most HMW DOM samples, the majority of the OM originates from terrigenous sources, with smaller contributions from riverine and estuarine phytoplankton. In contrast, the [C/N]a ratios of particulate OM (POM) samples varied significantly among the collection periods, ranging from low values of 5 to high values of >20. Overall, the trends in [C/N]a ratios indicated that algal sources of POM were most important during the early and late summer, whereas terrigenous sources dominated in the winter and early spring.In Winyah Bay bottom sediments, the concentrations of the mineral-associated OM were positively correlated with sediment surface area. The [C/N]a ratios and δ¹³C_OC compositions of the bulk sedimentary OM ranged from 5 to 45 and from −28 to −23‰, respectively. These compositions were consistent with predominant contributions of terrigenous sources and lesser (but significant) inputs of freshwater, estuarine and marine phytoplankton. The highest terrigenous contents were found in sediments from the river and upper bay sites, with smaller contributions to the lower parts of the estuary. The yields of lignin-derived CuO oxidation products from Winyah Bay sediments indicated that the terrigenous OM in these samples was composed of variable mixtures of relatively fresh vascular plant detritus and moderately altered soil OM. Based on the lignin phenol compositions, most of this material appeared to be derived from angiosperm and gymnosperm vascular plant sources similar to those found in the upland coastal forests in this region. A few samples displayed lignin compositions that suggested a more significant contribution from marsh C₃ grasses. However, there was no evidence of inputs of Spartina alterniflora (a C₄ grass) remains from the salt marshes that surround the lower sections of Winyah Bay.  相似文献   

Deposition Rates of Terrestrial and Marine Organic Carbon in the Osaka Bay, Seto Inland Sea, Japan, Determined Using Carbon and Nitrogen Stable Isotope Ratios in the Sediment   总被引：1，自引：0，他引：1  

Yasufumi Mishima  Akira Hoshika  Terumi Tanimoto 《Journal of Oceanography》1999,55(1):1-11

Carbon and nitrogen stable isotope ratios (¹³C and ¹⁵N) of surface sediments were measured within Osaka Bay, in the Seto Inland Sea in Japan, in order to better understand the sedimentation processes operating on both terrestrial and marine organic matter in the Bay. The ¹³C and ¹⁵N of surface sediments in the estuary of the Yodo River were less than –23 and 5 respectively, but increased in the area up to about 10 km from the river mouth. At greater distances they became constant (giving ¹³C of about –20 and ¹⁵N about 6). It can be concluded that large amounts of terrestrial organic matter exist near the mouth of the Yodo River. Stable isotope ratios in the estuary of the Yodo River within 10 km of the river mouth were useful indicators allowing study of the movement of terrestrial organic matter. Deposition rates for total organic carbon (TOC) and total nitrogen (TN) over the whole of the Bay were estimated to be 63,100 ton C/year and 7,590 ton N/year, respectively. The deposition rate of terrestrial organic carbon was estimated to be 13,200 (range 2,000–21,500) ton C/year for the whole of Osaka Bay, and terrestrial organic carbon was estimated to be about 21% (range 3–34) of the TOC deposition rate. The ratio of the deposition rate of terrestrial organic carbon to the rate inflow of riverine TOC and particulate organic carbon (POC) were estimated to be 19% (range 3–31) and 76% (range 12–100), respectively.  相似文献   

东海秋季典型站位沉降颗粒物通量   总被引：6，自引：0，他引：6  

张岩松  章飞军  郭学武  张曼平 《海洋与湖沼》2006,37(1):28-34

2002年9月在东海的长江口、中陆架区和浙江近岸上升流区三个站位放置沉积物捕获器采集沉降颗粒物。在对颗粒有机碳(POC)、颗粒有机氮(PON)和总颗粒碳(PC)元素分析基础上,采用颗粒物通量模型对沉降通量进行了研究。镜检发现细小无机颗粒物和大颗粒聚合体是三个站位沉降颗粒物的主要形式。大颗粒聚合体有住囊类、粪球聚合体、硅藻聚合体和混杂聚合体四种类型。研究结果显示,东海中陆架区和浙江近岸上升流区沉降颗粒物中POC、PON和PC的百分含量均呈现随水深增加明显降低的趋势,但在长江口,这些成分的含量低且上下均匀。长江口观测到的是大风后的一个实例,存在强烈的再悬浮,各水层颗粒物沉降通量平均(±SE)高达(319.02±65.33)g/(m2.d),尽管如此,沉降颗粒物有机态C/N值却很高(18.0±0.9),明显受陆源颗粒物的影响。POC净沉降通量在浙江近岸上升流区为961mg/(m2.d)(水深55m),在东海中陆架区为123mg/(m2.d)(水深88m),可见浙江近岸上升流区是POC向海底转移的重要区域之一,其垂直转移能力明显高于东海中陆架区。在上升流区域和中陆架区,POC的输出比率大约分别为48%—77%和15%—21%。浙江近岸上升流区和东海中陆架区底层颗粒物再悬浮比率分别为66.50%和88.52%。研究显示,浙江近岸上升流区的水体底层颗粒物受底部平流的影响比东海中陆架区相对较强。  相似文献   

黄河利津水文站不同粒径悬浮颗粒物中有机碳含量的研究   总被引：1，自引：0，他引：1  

刘立芳  张龙军  张向上 《中国海洋大学学报(自然科学版)》2006,36(Z1):126-130

估算不同粒径TSS中POC的入海日通量,对黄河利津水文站悬浮颗粒物(total suspended solid,TSS)样品,采用基于stokes原理的沉降法分为Ⅴ级,对分级后的样品测其有机碳(particulate organic carbon,POC)含量和粒度组成。在此基础上,用多元线性回归法对数据进一步处理,准确得到样品中不同粒径TSS中POC的含量。研究表明,黄河口淡水端水体TSS,<8μm的粘土和极细粉砂、8~16μm的细粉砂中,POC的含量为0.600%和0.400%左右;16~32μm的中粉砂中,POC的含量不足0.200%;而32~63μm的粗粉砂和>63μm砂中POC含量仅为0.050%和0.004%左右,80%以上的POC主要集中在<16μm的TSS中,而<32μm的TSS承载了95%以上的POC。  相似文献   

Particulate peptidoglycan in seawater determined by the silkworm larvae plasma (SLP) assay     

Akira Shibata  Kouichi Ohwada  Masakazu Tsuchiya  Kazuhiro Kogure 《Journal of Oceanography》2006,62(1):91-97

Peptidoglycan (PG) is a biopolymer found exclusively in the cell wall of bacteria. Recent chemical analysis of particulate organic matter suggests that a major amount of the muramic acid, an amino sugar present only in PG, could not be accounted for in terms of bacterial cells (Benner and Kaiser, 2003); however, data on particulate PG is quite sparse. In the present study, conducted in 1996, the PG was examined at 5 sampling sites in the northwestern Pacific Ocean, and in natural seawater cultures. Particulate PG, which was concentrated using a 96-well filtration plate equipped with Durapore filters (pore size, 0.22 μm), was measured by the silkworm larvae plasma (SLP) assay. The PG concentration generally decreased with depth and correlated significantly with bacterial abundance throughout the entire water column. However, the ratio of particulate PG to bacterial abundance varied with depth. The average ratio was 0.61 ± 0.53 (average ± SD, n = 40) between 50 and 2000 m, which agreed with the bacterial cellular PG content from 0.63 to 1.1 fg cell⁻¹ obtained in seawater cultures. On the other hand, the ratios of PG to bacteria from the surface to 50 m (3.7 ± 2.6, n = 29) and below 2,000 m (2.1 ± 1.7, n = 7) were significantly higher than that between 50 and 2,000 m. These results may suggest that, in the surface and deep layers, a significant fraction of particulate PG was present in bacterial detritus, whereas this fraction was reduced in the middle layer.  相似文献   

Benthic Standing Stock and Metabolic Activity in the Bathyal Red Sea from 17°N to 27°N     

Olaf  Pfannkuche 《Marine Ecology》1993,14(1):67-79

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Seasonal DOC accumulation in the Black Sea: a regional explanation for a general mechanism   总被引：2，自引：0，他引：2  

Gustave Cauwet  Gaëlle Dliat  Anton Krastev  Galina Shtereva  Sylvie Becquevort  Christiane Lancelot  Andr Momzikoff  Alain Saliot  Adriana Cociasu  Lucia Popa 《Marine Chemistry》2002,79(3-4)

During three cruises in the Black Sea, organised in July 1995 and April–May 1997, biological and chemical parameters that can influence the carbon budget were measured in the water column on the NW shelf, particularly in the mixing zone with Danube River waters. We observed in early spring (end of April–May) conditions an important input of freshwater organisms that enhanced the microbial activity in the low salinity range. High bacterial activity regenerates nitrogen in the form of nitrates, but is also responsible for an important consumption of ammonium and phosphate, leading to a high N/P ratio and a strong deficit in phosphorus. The consequence is a limitation of phytoplankton development but also a production of carbohydrates that accumulate all along the salinity gradient. These mechanisms are responsible for a seasonal accumulation of dissolved organic carbon (DOC) that increases from 210 μM in winter to about 280 μM in summer. All this excess DOC disappears during winter, probably degraded by bacterial activity. The degradation of carbon-rich organic matter increases the phosphorus demand by bacteria bringing limitation to phytoplankton primary production.  相似文献